ON THE PROBLEM OF CRYSTAL METALLIC LATTICE IN THE DENSEST PACKINGS OF CHEMICAL ELEMENTS

Abstract

The literature generally describes a metallic bond as the one formed by means of mutual bonds in the midst of portions exterior electrons and not possessing the directional properties. However, attempts have been made to pardon directional metallic bonds, as a specific quartz glass metallic lattice.

This paper demonstrates that the metallic bond in the densest packings (volume-centered and face-centered) among the centrally elected atom and its neighbours in general is, probably, established by 9 (nine) directional bonds, as opposed to the procedure of neighbours which equals 12 (twelve) (coordination number).

Probably, 3 (three) foreign atoms are present in the coordination number 12 stereometrically, and not for the reason of bond. This problem is to be solved experimentally.

Introduction

At present, it is impossible, as a general case, to derive by means of quantum-mechanical calculations the crystalline structure of metal in relation back to electronic structure of the atom. However, Hanzhorn and Dellinger indicated a possible relation between the presence of a cubical volume-centered lattice in subgroups of titanium, vanadium, chromium-plate and availability in these metals of valent d-orbitals.



It is easy to notice that the four interbreeding orbitals are tell along the four physical diagonals of the blockage and are well adjusted to natural covering each atom to its eight neighbours in the cubical volume-centered lattice, the remaining orbitals being directed towards the edge centers of the element cell and, possibly, participating in binding the atom to its six second neighbours /3/p. 99.

Let us sample to consider relations between exterior electrons of the atom of a given element and structure of its crystal lattice, accounting for the need of directional bonds (chemistry) and availability of combined electrons (physics) responsible for galvanic and magnetized properties.

According to /1/p. 20, the number of Z-electrons in the conductivitiy zone has been obtained by the authors, allegedly,

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